Synonym:
2,3-Butanedione dioxime,
Diacetyldioxime
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CAS Number 95-45-4
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Linear Formula CH3C(=NOH)C(=NOH)CH3
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Molecular Weight 116.12
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Beilstein Registry Number 506731
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EC Number 202-420-1
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MDL number MFCD00002117
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PubChem Substance ID 329755984
Properties:
| Related Categories |
Analytical Reagents,
Analytical Reagents for General Use,
Analytical/Chromatography,
C-D, Puriss p.a. ACS,
Derivatization Reagents,
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grade
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ACS reagent
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InChI Key
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JGUQDUKBUKFFRO-GGWOSOGESA-N
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grade
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puriss. p.a.
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assay
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≥99.0% (TLC)
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quality
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for the detection of Ni
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impurities
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≤0.02% insoluble matter in ethanol
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ign. residue
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≤0.05% (as SO4)
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mp
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240-241 °C(lit.)
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solubility
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water: soluble 0.1 g/10 mL clear, colorless
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cation traces
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Ca: ≤10 mg/kg
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Cd: ≤5 mg/kg
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Co: ≤5 mg/kg
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Cr: ≤5 mg/kg
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Cu: ≤5 mg/kg
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Fe: ≤5 mg/kg
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K: ≤50 mg/kg
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Mg: ≤5 mg/kg
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Mn: ≤5 mg/kg
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Na: ≤50 mg/kg
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Ni: ≤5 mg/kg
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Pb: ≤5 mg/kg
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Zn: ≤5 mg/kg
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storage temp.
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2-8°C
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Description:
Application
Dimethylglyoxime (DMG) was used as complexing agent for cobalt(II) and nickel(II) metals for the analysis of brine for trace metals by adsorptive stripping voltammetry. DMG was used in a study to develop a new DMG containing modified sol-gel carbon composite electrode for voltammetric sensing of heavy metals.
General description
Dimethylglyoxime (DMG) is a complexing ligand. Dimethylglyoxime forms a number of mixed ligand complexes with N-acetylglycine with metals such as VO(IV), Ni(II), Zn(II), Pd(II), Cd(II) and Pb(II). It is a useful reagent for the spectrophotometric determination of Co(II), Fe(II), Ni(II), Pd(II) and Re(VII).
Safety:
Symbol

GHS02
Precautionary statements
P210-P370 + P378
Personal Protective Equipment
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RIDADR
UN 2926 6.1(4.1) / PGIII