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            當前位置 : Sigma-Aldrich >>> Sigma-Aldrich/Ethyl acetate/439169-4L/4L
            Sigma-Aldrich/Ethyl acetate/439169-4L/4L
            • Sigma-Aldrich/Ethyl acetate/439169-4L/4L

            Sigma-Aldrich/Ethyl acetate/439169-4L/4L

            價格: ¥1879.10 市場價: 2442.83

            貨號: 439169-4L
            品牌: Sigma-Aldrich
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              • Synonym: EtOAc
                • CAS Number 141-78-6

                • Linear Formula CH3COOC2H5

                • Molecular Weight 88.11

                •  Beilstein Registry Number 506104

                •  EC Number 205-500-4

                •  MDL number MFCD00009171

                •  PubChem Substance ID 329756423

                Properties:

                Related Categories Analytical Reagents, Analytical/Chromatography, Chromatography Reagents & Solvents, Ethyl Acetate, HPLC,
                More...
                grade   for HPLC
                vapor density   3 (20 °C, vs air)
                vapor pressure   73 mmHg ( 20 °C)
                InChI Key   XEKOWRVHYACXOJ-UHFFFAOYSA-N
                assay   ≥99.8%
                autoignition temp.   801 °F
                expl. lim.   2.2-11.5 %, 38 °F
                impurities   <0.050% water
                evapn. residue   <0.0003%
                refractive index   n20/D 1.3720(lit.)
                bp   76.5-77.5 °C(lit.)
                mp   −84 °C(lit.)
                solubility   alcohol: soluble(lit.)
                  chloroform: soluble(lit.)
                density   0.902 g/mL at 25 °C(lit.)
                λ   H2O reference
                UV absorption   λ: 254 nm Amax: 1.00
                  λ: 263 nm Amax: 0.05
                  λ: 275-400 nm Amax: 0.01

                Description:

                Packaging

                2×10, 20 L in Nowpak™

                20 L in Pure-Pac™ 2

                4, 4×4 L in PVC-coated bottle

                50 L in composite drum

                Application

                Ethyl acetate may be used in the following studies:
                • As solvent for the isolation of Rose hip (Rosa canina L., Rosaceae) powder, via sonication.
                • As solvent for the abstraction of volatile thiols from wine for their quantitative estimation by gas chromatography/mass spectrometry (GC-MS).
                • Preparation of thin films of TiO2 (titanium dioxide) on glass.
                • As an extraction medium in the multi-residue analysis of pesticide residues in fruit and vegetables.
                • Acetylation of primary amines to form amides in the presence of dimethyltin(IV) acetic acid distannoxane.

                General description

                Ethyl acetate (EA), a carboxylate ester, is bio-friendly organic solvent with a wide range of industrial applications. Its synthesis by reactive distillation and by acceptorless dehydrogenative dimerization of ethanol has been explored. Its ability as an acyl acceptor in the immobilized lipase-mediated preparation of biodiesel from crude vegetable oils has been examined. The complete degradation of ethyl acetate to CO2 using manganese octahedral molecular sieve (OMS-2) has been investigated. EA is an effective alternate solvent of diethyl ether, employed for the concentration of eggs, larvae, and cysts in fecal specimens during the Formalin-ether sedimentation technique. Acetaldehyde is reaction intermediate formed during the oxidative combustion of ethanol and ethyl acetate in the presence of copper oxide embedded on Ce-doped titania surface.

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                Safety:

                Symbol 
                GHS02GHS07  GHS02, GHS07
                Signal word 
                Danger
                Hazard statements 
                H225-H319-H336
                Precautionary statements 
                P210-P305 + P351 + P338-P370 + P378-P403 + P235
                Supplemental Hazard Statements 
                Repeated exposure may cause skin dryness or cracking.
                RIDADR 
                UN1173 - class 3 - PG 2 - Ethyl acetate
                WGK Germany 
                1
                RTECS 
                AH5425000
                Flash Point(F) 
                26.6 °F
                Flash Point(C) 
                -3 °C
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